Concrete is a composite construction material, composed of cement (commonly Portland cement) and other cementitious materials such as fly ash and slag cement, aggregate (generally a coarse aggregate made of gravel or crushed rocks such as limestone, or granite, plus a fine aggregate such as sand), water and chemical admixtures.
The word concrete comes from the Latin word "concretus" (meaning compact or condensed), the perfect passive participle of "concrescere", from "con-" (together) and "crescere" (to grow).
Concrete solidifies and hardens after mixing with water and placement due to a chemical process known as hydration. The water reacts with the cement, which bonds the other components together, eventually creating a robust stone-like material. Concrete is used to make pavements, pipe, architectural structures, foundations, motorways/roads, bridges/overpasses, parking structures, brick/block walls, footings for gates, fences and poles and even boats.
Concrete is used more than any other man-made material in the world.[2] As of 2006, about 7.5 billion cubic meters of concrete are made each year—more than one cubic meter for every person on Earth.[3]
Concrete powers a US$35 billion industry, employing more than two million workers in the United States alone. More than 55,000 miles (89,000 km) of highways in the United States are paved with this material. Reinforced concrete, prestressed concrete and precast concrete are the most widely used types of concrete functional extensions in modern days.
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Concrete was used for construction in many ancient structures.[4]
During the Roman Empire, Roman concrete (or opus caementicium) was made from quicklime, pozzolana and an aggregate of pumice. Its widespread use in many Roman structures, a key event in the history of architecture termed the Roman Architectural Revolution, freed Roman construction from the restrictions of stone and brick material and allowed for revolutionary new designs in terms of both structural complexity and dimension.[5]
Concrete, as the Romans knew it, was a new and revolutionary material. Laid in the shape of arches, vaults and domes, it quickly hardened into a rigid mass, free from many of the internal thrusts and strains that troubled the builders of similar structures in stone or brick.[6]
Modern tests show that opus caementicium had as much compressive strength as modern Portland-cement concrete (ca. 200 kg/cm2).[7] However, due to the absence of steel reinforcement, its tensile strength was far lower and its mode of application was also different:
Modern structural concrete differs from Roman concrete in two important details. First, its mix consistency is fluid and homogeneous, allowing it to be poured into forms rather than requiring hand-layering together with the placement of aggregate, which, in Roman practice, often consisted of rubble. Second, integral reinforcing steel gives modern concrete assemblies great strength in tension, whereas Roman concrete could depend only upon the strength of the concrete bonding to resist tension.[8]
The widespread use of concrete in many Roman structures has ensured that many survive to the present day. The Baths of Caracalla in Rome are just one example. Many Roman aqueducts and bridges have masonry cladding on a concrete core, as does the dome of the Pantheon.
Some have stated that the secret of concrete was lost for 13 centuries until 1756, when the British engineer John Smeaton pioneered the use of hydraulic lime in concrete, using pebbles and powdered brick as aggregate. However, the Canal du Midi was built using concrete in 1670.[9] Likewise there are concrete structures in Finland that date back to the 16th century. Portland cement was first used in concrete in the early 1840s.
Concrete additives have been used since Roman and Egyptian times, when it was discovered that adding volcanic ash to the mix allowed it to set under water. Similarly, the Romans knew that adding horse hair made concrete less liable to crack while it hardened and adding blood made it more frost-resistant.[10]
Recently the use of recycled materials as concrete ingredients has been gaining popularity because of increasingly stringent environmental legislation. The most conspicuous of these is fly ash, a by-product of coal-fired power plants. This use reduces the amount of quarrying and landfill space required as the ash acts as a cement replacement thus reducing the amount of cement required.
In modern times, researchers have experimented with the addition of other materials to create concrete with improved properties, such as higher strength or electrical conductivity. Marconite is one example.
There are many types of concrete available, created by varying the proportions of the main ingredients below. In this way or by substitution for the cemetitious and aggregate phases, the finished product can be tailored to its application with varying strength, density, or chemical and thermal resistance properties.
The mix design depends on the type of structure being built, how the concrete will be mixed and delivered and how it will be placed to form this structure.
Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar and plaster. English masonry worker Joseph Aspdin patented Portland cement in 1824; it was named because of its similarity in color to Portland limestone, quarried from the English Isle of Portland and used extensively in London architecture. It consists of a mixture of oxides of calcium, silicon and aluminium. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay and grinding this product (called clinker) with a source of sulfate (most commonly gypsum).
In recent years, alternatives have been developed to help replace cement. Products such as PLC (Portland Limestone Cement)[11] , which incorporate limestone into the mix, are being tested. A big reason for this is that Cement production is one of the largest producers of Green House Gas (GHG) emissions in the world.
Combining water with a cementitious material forms a cement paste by the process of hydration. The cement paste glues the aggregate together, fills voids within it and allows it to flow more freely.
Less water in the cement paste will yield a stronger, more durable concrete; more water will give a freer-flowing concrete with a higher slump. Impure water used to make concrete can cause problems when setting or in causing premature failure of the structure.
Hydration involves many different reactions, often occurring at the same time. As the reactions proceed, the products of the cement hydration process gradually bond together the individual sand and gravel particles and other components of the concrete, to form a solid mass.
Reaction:
Fine and coarse aggregates make up the bulk of a concrete mixture. Sand, natural gravel and crushed stone are used mainly for this purpose. Recycled aggregates (from construction, demolition and excavation waste) are increasingly used as partial replacements of natural aggregates, while a number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted.
Decorative stones such as quartzite, small river stones or crushed glass are sometimes added to the surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers.
The presence of aggregate greatly increases the robustness of concrete above that of cement, which otherwise is a brittle material and thus concrete is a true composite material.
Redistribution of aggregates after compaction often creates inhomogeneity due to the influence of vibration. This can lead to strength gradients.[12]
Concrete is strong in compression, as the aggregate efficiently carries the compression load. However, it is weak in tension as the cement holding the aggregate in place can crack, allowing the structure to fail. Reinforced concrete solves these problems by adding either steel reinforcing bars, steel fibers, glass fiber, or plastic fiber to carry tensile loads. Thereafter the concrete is reinforced to withstand the tensile loads upon it.
Chemical admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. In normal use, admixture dosages are less than 5% by mass of cement and are added to the concrete at the time of batching/mixing.[13] The common types of admixtures[14] are as follows.
There are inorganic materials that also have pozzolanic or latent hydraulic properties. These very fine-grained materials are added to the concrete mix to improve the properties of concrete (mineral admixtures),[13] or as a replacement for Portland cement (blended cements).[15]
The processes used vary dramatically, from hand tools to heavy industry, but result in the concrete being placed where it cures into a final form. Wide range of technological factors may occur during production of concrete elements and their influence to basic characteristics may vary.[19]
When initially mixed together, Portland cement and water rapidly form a gel, formed of tangled chains of interlocking crystals. These continue to react over time, with the initially fluid gel often aiding in placement by improving workability. As the concrete sets, the chains of crystals join and form a rigid structure, gluing the aggregate particles in place. During curing, more of the cement reacts with the residual water (hydration).
This curing process develops physical and chemical properties. Among these qualities are mechanical strength, low moisture permeability and chemical and volumetric stability.
Thorough mixing is essential for the production of uniform, high quality concrete. For this reason equipment and methods should be capable of effectively mixing concrete materials containing the largest specified aggregate to produce uniform mixtures of the lowest slump practical for the work.
Separate paste mixing has shown that the mixing of cement and water into a paste before combining these materials with aggregates can increase the compressive strength of the resulting concrete.[20] The paste is generally mixed in a high-speed, shear-type mixer at a w/cm (water to cement ratio) of 0.30 to 0.45 by mass. The cement paste premix may include admixtures such as accelerators or retarders, superplasticizers, pigments, or silica fume. The premixed paste is then blended with aggregates and any remaining batch water and final mixing is completed in conventional concrete mixing equipment.[21]
High-energy mixed (HEM) concrete is produced by means of high-speed mixing of cement, water and sand with net specific energy consumption of at least 5 kilojoules per kilogram of the mix. A plasticizer or a superplasticizer is then added to the activated mixture, which can later be mixed with aggregates in a conventional concrete mixer. In this process, sand provides dissipation of energy and creates high-shear conditions on the surface of cement particles. This results in the full volume of water interacting with cement. The liquid activated mixture can be used by itself or foamed (expanded) for lightweight concrete.[22] HEM concrete hardens in low and subzero temperature conditions and possesses an increased volume of gel, which drastically reduces capillarity in solid and porous materials.
Workability is the ability of a fresh (plastic) concrete mix to fill the form/mold properly with the desired work (vibration) and without reducing the concrete's quality. Workability depends on water content, aggregate (shape and size distribution), cementitious content and age (level of hydration) and can be modified by adding chemical admixtures, like superplasticizer. Raising the water content or adding chemical admixtures will increase concrete workability. Excessive water will lead to increased bleeding (surface water) and/or segregation of aggregates (when the cement and aggregates start to separate), with the resulting concrete having reduced quality. The use of an aggregate with an undesirable gradation can result in a very harsh mix design with a very low slump, which cannot be readily made more workable by addition of reasonable amounts of water.
Workability can be measured by the concrete slump test, a simplistic measure of the plasticity of a fresh batch of concrete following the ASTM C 143 or EN 12350-2 test standards. Slump is normally measured by filling an "Abrams cone" with a sample from a fresh batch of concrete. The cone is placed with the wide end down onto a level, non-absorptive surface. It is then filled in three layers of equal volume, with each layer being tamped with a steel rod in order to consolidate the layer. When the cone is carefully lifted off, the enclosed material will slump a certain amount due to gravity. A relatively dry sample will slump very little, having a slump value of one or two inches (25 or 50 mm). A relatively wet concrete sample may slump as much as eight inches. Workability can also be measured by using the flow table test.
Slump can be increased by addition of chemical admixtures such as plasticizer or superplasticizer without changing the water-cement ratio. Some other admixtures, especially air-entraining admixture, can increase the slump of a mix.
High-flow concrete, like self-consolidating concrete, is tested by other flow-measuring methods. One of these methods includes placing the cone on the narrow end and observing how the mix flows through the cone while it is gradually lifted.
After mixing, concrete is a fluid and can be pumped to the location where needed.
In all but the least critical applications, care needs to be taken to properly cure concrete, to achieve best strength and hardness. This happens after the concrete has been placed. Cement requires a moist, controlled environment to gain strength and harden fully. The cement paste hardens over time, initially setting and becoming rigid though very weak and gaining in strength in the weeks following. In around 3 weeks, typically over 90% of the final strength is reached, though strengthening may continue for decades.[23] The conversion of calcium hydroxide in the concrete into calcium carbonate from absorption of CO2 over several decades further strengthen the concrete and making it more resilient to damage. However, this reaction, called carbonation, lowers the pH of the cement pore solution and can cause the reinforcement bars to corrode.
Hydration and hardening of concrete during the first three days is critical. Abnormally fast drying and shrinkage due to factors such as evaporation from wind during placement may lead to increased tensile stresses at a time when it has not yet gained sufficient strength, resulting in greater shrinkage cracking. The early strength of the concrete can be increased if it is kept damp during the curing process. Minimizing stress prior to curing minimizes cracking. High-early-strength concrete is designed to hydrate faster, often by increased use of cement that increases shrinkage and cracking. Strength of concrete changes (increases) up to three years. It depends on cross-section dimension of elements and conditions of structure exploitation.[24]
During this period concrete needs to be kept under controlled temperature and humid atmosphere. In practice, this is achieved by spraying or ponding the concrete surface with water, thereby protecting the concrete mass from ill effects of ambient conditions. The pictures to the right show two of many ways to achieve this, ponding – submerging setting concrete in water and wrapping in plastic to contain the water in the mix. Additional common curing methods include wet burlap and/or plastic sheeting covering the fresh concrete, or by spraying on a water-impermeable temporary curing membrane.
Properly curing concrete leads to increased strength and lower permeability and avoids cracking where the surface dries out prematurely. Care must also be taken to avoid freezing, or overheating due to the exothermic setting of cement. Improper curing can cause scaling, reduced strength, poor abrasion resistance and cracking.
Concrete has relatively high compressive strength, but much lower tensile strength. For this reason is usually reinforced with materials that are strong in tension (often steel). The elasticity of concrete is relatively constant at low stress levels but starts decreasing at higher stress levels as matrix cracking develops. Concrete has a very low coefficient of thermal expansion and shrinks as it matures. All concrete structures will crack to some extent, due to shrinkage and tension. Concrete that is subjected to long-duration forces is prone to creep.
Tests can be made to ensure the properties of concrete correspond to specifications for the application.
The cement industry is one of two primary producers of carbon dioxide (CO2), creating up to 5% of worldwide man-made emissions of this gas, of which 50% is from the chemical process and 40% from burning fuel.[25] The carbon dioxide (CO2) produced for the manufacture of one tonne of structural concrete (using ~14% cement) is estimated at 410 kg/m3 (~180 kg/tonne @ density of 2.3g/cm3) (reduced to 290 kg/m3 with 30% fly ash replacement of cement).[26] The CO2 emission from the concrete production is directly proportional to the cement content used in the concrete mix; 900 kg of CO2 are emitted for the fabrication of every ton of cement.[27] Cement manufacture contributes greenhouse gases both directly through the production of carbon dioxide when calcium carbonate is thermally decomposed, producing lime and carbon dioxide,[28] and also through the use of energy, particularly from the combustion of fossil fuels.
Surface runoff, when water runs off impervious surfaces, such as non-porous concrete, can cause heavy soil erosion and flooding. Urban runoff tends to pick up gasoline, motor oil, heavy metals, trash and other pollutants from sidewalks, roadways and parking lots.[29][30] Without attenuation, the impervious cover in a typical urban area limits groundwater percolation and causes five times the amount of runoff generated by a typical woodland of the same size.[31] A 2008 report by the United States National Research Council identified urban runoff as a leading source of water quality problems.[32]
Both concrete and asphalt are the primary contributors to what is known as the urban heat island effect.
Using light-colored concrete has proven effective in reflecting up to 50% more light than asphalt and reducing ambient temperature.[33] A low albedo value, characteristic of black asphalt, absorbs a large percentage of solar heat and contributes to the warming of cities. By paving with light colored concrete, in addition to replacing asphalt with light-colored concrete, communities can lower their average temperature.[34]
In many U.S. cities, pavement covers about 30–40% of the surface area.[33] This directly affects the temperature of the city and contributes to the urban heat island effect. Paving with light-colored concrete would lower temperatures of paved areas and improve night-time visibility.[33] The potential of energy saving within an area is also high. With lower temperatures, the demand for air conditioning decreases, saving energy.
Atlanta has tried to mitigate the heat-island effect. City officials noted that when using heat-reflecting concrete, their average city temperature decreased by 6°F (3.3°C).[35] The Design Trust for Public Space found that by slightly raising the albedo value in New York City, beneficial effects such as energy savings could be achieved. It was concluded that this could be accomplished by the replacement of black asphalt with light-colored concrete.
However, in winter this may be a disadvantage as ice will form more easily and remain longer on the light colored surfaces as they will be colder due to less energy absorbed from the reduced amount of sunlight in winter.[34]
Building demolition and natural disasters such as earthquakes often release a large amount of concrete dust into the local atmosphere. Concrete dust was concluded to be the major source of dangerous air pollution following the Great Hanshin earthquake.
The presence of some substances in concrete, including useful and unwanted additives, can cause health concerns. Natural radioactive elements (K, U and Th) can be present in various concentration in concrete dwellings, depending on the source of the raw materials used.[36] Toxic substances may also be added to the mixture for making concrete by unscrupulous makers. Dust from rubble or broken concrete upon demolition or crumbling may cause serious health concerns depending also on what had been incorporated in the concrete.
Handling of wet concrete must always be done with proper protective equipment. Contact with wet concrete can cause skin chemical burns due to the caustic nature of the mixture of cement and water. Indeed, the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution (pH ~ 13.5). Eyes, hands and feet must be correctly protected to avoid any direct contact with wet concrete and washed without delay if necessary.
Concrete can be damaged by many processes, such as the expansion of corrosion products of the steel reinforcement bars, freezing of trapped water, fire or radiant heat, aggregate expansion, sea water effects, bacterial corrosion, leaching, erosion by fast-flowing water, physical damage and chemical damage (from carbonation, chlorides, sulfates and distillate water).
Concrete recycling is an increasingly common method of disposing of concrete structures. Concrete debris was once routinely shipped to landfills for disposal, but recycling is increasing due to improved environmental awareness, governmental laws and economic benefits.
Concrete, which must be free of trash, wood, paper and other such materials, is collected from demolition sites and put through a crushing machine, often along with asphalt, bricks and rocks.
Reinforced concrete contains rebar and other metallic reinforcements, which are removed with magnets and recycled elsewhere. The remaining aggregate chunks are sorted by size. Larger chunks may go through the crusher again. Smaller pieces of concrete are used as gravel for new construction projects. Aggregate base gravel is laid down as the lowest layer in a road, with fresh concrete or asphalt placed over it. Crushed recycled concrete can sometimes be used as the dry aggregate for brand new concrete if it is free of contaminants, though the use of recycled concrete limits strength and is not allowed in many jurisdictions. On 3 March 1983, a government funded research team (the VIRL research.codep) approximated that almost 17% of worldwide landfill was by-products of concrete based waste.
The world record for the largest concrete pour in a single project is the Three Gorges Dam in Hubei Province, China by the Three Gorges Corporation. The amount of concrete used in the construction of the dam is estimated at 16 million cubic meters over 17 years. The previous record was 3.2 million cubic meters held by Itaipu hydropower station in Brazil.[37][38]
The world record was set at on 7 August 2009 during the construction of the Parbati Hydroelectric Project, near the village of Suind, Himachal Pradesh, India, when the concrete mix was pumped through a vertical height of 715 m (2,346 ft).[39][40]
The world record for largest continuously poured concrete raft was achieved in August 2007 in Abu Dhabi by contracting firm Al Habtoor-CCC Joint Venture. The pour (a part of the foundation for the Abu Dhabi's Landmark Tower) was 16,000 cubic meters of concrete poured within a two day period.[41] The previous record (close to 10,500 cubic meters) was held by Dubai Contracting Company and achieved 23 March 2007.[42]
The world record for largest continuously poured concrete floor was completed 8 November 1997, in Louisville, Kentucky by design-build firm EXXCEL Project Management. The monolithic placement consisted of 225,000 square feet (20,900 m2) of concrete placed within a 30 hour period, finished to a flatness tolerance of FF 54.60 and a levelness tolerance of FL 43.83. This surpassed the previous record by 50% in total volume and 7.5% in total area.[43][44]
The record for the largest continuously placed underwater concrete pour was completed 18 October 2010, in New Orleans, Louisiana by contractor C. J. Mahan Construction Company, LLC of Grove City, Ohio. The placement consisted of 10,224 cubic yards of concrete placed in a 58 hour period using two concrete pumps and two dedicated concrete batch plants. Upon curing, this placement will allow the 50,180-square-foot (4,662 m2) cofferdam to be dewatered approximately 26 feet (7.9 m) below sea level to allow the construction of the IHNC GIWW Sill & Monolith Project to be completed in the dry.
These large structures typically include gravity dams, such as the Hoover Dam, the Itaipu Dam and the Three Gorges Dam, arch dams, navigation locks and large breakwaters. Such large structures, even though individually placed in formed horizontal blocks, generate excessive heat and associated expansion; to mitigate these effects post-cooling[45] is commonly provided in the design. An early example at Hoover Dam, installed a network of pipes between vertical concrete placements to circulate cooling water during the curing process to avoid damaging overheating. Similar systems are still used; depending on volume of the pour, the concrete mix used, and ambient air temperature, the cooling process may last for many months after the concrete is placed. Various methods also are used to pre-cool the concrete mix in mass concrete structures.[45]
Concrete that is poured all at once in one form (so that there are no weak points where the concrete is "welded" together) is used for tornado shelters.
Reinforced concrete contains steel reinforcing that is designed and placed in the structure at specific positions to cater for all the stress conditions that the structure is required to accommodate.
Pre-stressed concrete is a form of reinforced concrete that builds in compressive stresses during construction to oppose those found when in use. This can greatly reduce the weight of beams or slabs, by better distributing the stresses in the structure to make optimal use of the reinforcement. For example a horizontal beam will tend to sag down. If the reinforcement along the bottom of the beam is pre-stressed, it can counteract this.
In pre-tensioned concrete, the pre-stressing is achieved by using steel or polymer tendons or bars that are subjected to a tensile force prior to casting, or for post-tensioned concrete, after casting.
When one thinks of concrete, the image of a dull, gray concrete wall often comes to mind. With the use of form liner, concrete can be cast and molded into different textures and used for decorative concrete applications. Sound/retaining walls, bridges, office buildings and more serve as the optimal canvases for concrete art. For example, the Pima Freeway/Loop 101 retaining and sound walls in Scottsdale, Arizona, feature desert flora and fauna, a 67-foot (20 m) lizard and 40-foot (12 m) cacti along the 8-mile (13 km) stretch. The project, titled "The Path Most Traveled," is one example of how concrete can be shaped using elastomeric form liner.
Concrete is one of the most durable building materials. It provides superior fire resistance, compared with wooden construction and can gain strength over time. Structures made of concrete can have a long service life. Concrete is the most widely used construction material in the world with annual consumption estimated at between 21 and 31 billion tonnes.
Energy requirements for transportation of concrete are low because it is produced locally from local resources, typically manufactured within 100 kilometers of the job site. Once in place, concrete offers significant energy efficiency over the lifetime of a building.[46] Concrete walls leak air far less than those made of wood-frames. Air leakage accounts for a large percentage of energy loss from a home. The thermal mass properties of concrete increase the efficiency of both residential and commercial buildings. By storing and releasing the energy needed for heating or cooling, concrete's thermal mass delivers year-round benefits by reducing temperature swings inside and minimizing heating and cooling costs . While insulation reduces energy loss through the building envelope, thermal mass uses walls to store and release energy. Modern concrete wall systems use both insulation and thermal mass to create an energy-efficient building. Insulating Concrete Forms (ICFs) are hollow blocks or panels made of either insulating foam or rastra that are stacked to form the shape of the walls of a building and then filled with reinforced concrete to create the structure.
Concrete buildings are more resistant to fire than those constructed using wood or steel frames, since concrete does not burn. Concrete reduces the risk of structural collapse and is an effective fire shield, providing safe means of escape for occupants and protection for fire fighters.
Options for non-combustible construction include floors, ceilings and roofs made of cast-in-place and hollow-core precast concrete. For walls, concrete masonry technology and Insulating Concrete Forms (ICFs) are additional options. ICFs are hollow blocks or panels made of fire-proof insulating foam that are stacked to form the shape of the walls of a building and then filled with reinforced concrete to create the structure.
Concrete also provides the best resistance of any building material to high winds, hurricanes, tornadoes due to its lateral stiffness that results in minimal horizontal movement.
As discussed above, concrete is very strong in compression, but weak in tension. Larger earthquakes can generate very large shear loads on structures. These shear loads subject the structure to both tensional and compressional loads. Concrete structures without reinforcing, like other unreinforced masonry structures, can fail during severe earthquake shaking. Unreinforced masonry structures constitute one of the largest earthquake risks globally[47]. These risks can be reduced through seismic retrofitting of at-risk buildings, (e.g. School buildings in Istanbul, Turkey[48]).
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